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Chemical News
Dust explosion, explosion, explosion prevention - how to achieve "explosion without explosion" 发布日期:【2023-07-25】 / 浏览次数:【13733】次

Dust explosions often occur in production and processing sites accompanied by aluminum powder, magnesium powder, zinc powder, zirconium powder, cobalt powder, iron powder, aluminum processing grinding powder, PCB cutting, PCB destruction, various plastic powders, intermediates of organic synthetic drugs, corn starch, wheat flour, sugar, sawdust, dyes, bakelite ash, milk powder, tea leaf powder, tobacco powder, coal dust, plant fiber dust, etc. The personnel injuries and property losses caused by dust explosions are incalculable, such as the explosion at the Kunshan factory in Jiangsu on August 2, 2014, which resulted in 75 deaths. Explosion is a safety accident caused by aluminum dust encountering open flames. To save unnecessary and irreversible losses and protect the personal safety of workshop personnel, strict compliance with production regulations should be implemented to prevent accidents before they occur.

1、 Formation of dust explosion

粉尘防爆

Dust explosion refers to the phenomenon where dust particles suspended in the air and rapidly burning within the explosive limit range cause flame propagation, resulting in high temperatures and high pressures in a relatively enclosed space. For example, a pile of flour is difficult to ignite with an open flame, but when we blow this pile of flour into a closed space, it forms dust and comes into full contact with the air. When encountering an open flame, the entire space of flour dust is ignited instantly. Imagine if in mass production, the flour dust inside the entire workshop is ignited by an open flame, resulting in a huge explosion power and incalculable personal injury and property damage.


2、 Related industries involved in dust explosions

1. Grain, food processing, feed

Grain depot, flour mill, food processing plant, feed mill

2. Wood processing

Door companies, flooring factories, timber factories, furniture factories

3. Metal powder production

Magnesium powder, aluminum powder and other powder production factories

4. Metal processing

Automotive parts factories (wheels, brake pads, front grille, decorative strips), aluminum alloy parts factories (cylinders for pneumatic valves), precision metal processing enterprises (laptop, tablet, and mobile phone frames), locks, motorcycle parts, hardware daily necessities, other aluminum products, titanium alloy processing.

5. Production and processing of plastics and resins

Plastic and powder production, spray coating, wind turbine blades, PVC pipes, synthetic resins

6. Light Industry

Food deep processing (starch, glucose, fructose), sugar, instant noodles, various blended beverages (coffee, milk powder), seasoning factories (dry seasoning, soy sauce factories), malt factories, breweries.

Pharmaceuticals, pesticides, dyes

Tea and tobacco

7. Chemical industry

Sulfur, coal chemical industry, petroleum coke

8. Energy and Building Materials

Thermal power generation, cement, ironmaking

9. Textile

Linen, cotton textile, synthetic fiber textile, down product factory

10. Port

Coal terminal, grain terminal

11. Solid waste treatment

Destruction of printers, copiers, and computers

Destruction of PCB circuit board

other


threeTheIn productionFormation of dust clouds

· The continuous existence of dust/air mixture due to the process itself

For example, lifting (bucket elevator, belt clamp), horizontal conveying (buried scraper, belt conveyor), crushing, mixing, rotary drying, spray drying, fluidized bed drying, pneumatic conveying, dust removal, etc.

· Sedimentary dust is disturbed during maintenance and cleaning processes

· The shock wave generated by the initial explosion lifts up the deposited dust layer.

· Dust combustion leads to the peeling and falling of the dust layer

 

4Types of dust involved in dust explosions

1. Grain, agricultural products, and food dust

For example, corn starch, wheat flour, coffee, sugar, milk powder, soybean flour, fish bone powder, mixed feed, tobacco, corn cob, etc.

2. Wood dust

This includes associated dust generated during wood processing, wood powder (used for producing cellulose), and debris from papermaking and wood based pellet biofuels.

3. Metal powder or metal dust

For example, aluminum powder, magnesium powder, zinc powder, zirconium powder, cobalt powder, iron powder, etc.

4. Non metallic elemental substance

For example, sulfur, phosphorus, silicon, etc.

5. Polymers such as plastics and synthetic resins

ABS、 Polyethylene, polypropylene, phenolic resin, epoxy resin, etc.

6. Coal based substances

Lignite, bituminous coal, anthracite, peat, coke, petroleum coke, etc.

7. Chemical dust

Pharmaceutical industry dust

Herbicides and insecticides

intermediate

Antioxidants, slow-release agents

8. Textile fibers

Including natural fibers (such as cotton, linen, wool, down) and chemical fibers (such as polyester, spandex, acrylic, etc.)

 

5Five elements of dust explosion1. Combustible dust; 2. Oxygen; 3. Fire source; 4. Restricted space; 5. Spread.

粉尘涉爆

VIThe development of dust explosionsprocess

The first step is the rapid dry distillation or gasification of suspended dust under the action of a heat source to produce combustible gases; The second step is to mix combustible gas with air and burn it; The third step is to transfer the heat released by the combustion of dust to nearby suspended or blown dust through thermal conduction and flame radiation. These dust particles are heated and vaporized, causing the combustion cycle to continue. As each ring is laid, the reaction rate gradually increases, and through intense combustion, an explosion is formed. This explosion reaction, as well as the speed of the explosion flame, explosion wave, explosion pressure, etc., will continue to accelerate and increase, and develop in a leapfrog manner.


7Main hazards1. It has extremely strong destructive power; 2. It is prone to secondary explosions. The first explosion wave blows up the dust deposited on the equipment or ground. In a short period of time after the explosion, negative pressure is formed in the central area of the explosion, and fresh air around fills in from the outside to the inside, forming a so-called "return wind". It mixes with the raised dust and ignites the second explosion under the residual fire of the first explosion. During the second explosion, the dust concentration is generally much higher than during the first explosion, so the power of the second explosion is much greater than that of the first one. 3. It can produce toxic gases, mainly carbon monoxide and toxic gases from the decomposition of the explosive itself.


8、 Dust testing standards and testing items

 

number

Test project

Testing standards

significance

practical application

1

Dust small ignition energy

GB/T 16428
ASTM E2019

The small value of ignition source energy that ignites and maintains combustion in the dust cloud.

The small ignition energy is the basis for selecting explosion-proof methods. If the ignition energy MIE of dust is less than 10mJ, the dust is more likely to be ignited, and inert methods for explosion prevention should usually be considered.

2

Explosive nature of dust clouds

ASTM E1226
VDI 2263/GB/T 16426

Determine whether the dust itself has explosiveness.

Determine whether dust explosion protection is necessary.

3

Lower limit of dust cloud explosion

GB∕T 16425
ASTM E 1515/VDI 2263

Reflects the low concentration of combustible dust that maintains the dust cloud just enough for flame propagation during atmospheric and room temperature explosions

Used to control the dust concentration in process equipment and pipelines below the lower explosive limit to prevent explosions from occurring.

4

Dust explosion index Kst (including high pressure and rising rate of dust explosion)

ASTM E1226
VDI 2263/GB/T 16426

An important parameter reflecting the intensity of an explosion, the explosion index characterizes the rate of pressure rise and indirectly reflects the speed of flame propagation.

Used for explosion pressure relief design, explosion suppression design, environmental ventilation, isolation, and partial inerting.

5

Ultimate oxygen content of dust cloud

ASTM E 2931
DIN EN 14034-4 /VDI 2263

The small percentage of oxygen content that can sustainably spread flames in dust clouds.

A mixture of dust, inert gas, and oxygen with high oxygen concentration that does not cause explosions.

Control and monitoring of oxygen content, inerting treatment.

6

Low ignition temperature of dust cloud

GB∕T 16429
ASTM E 1491/VDI 2263

The low ignition temperature of dust clouds refers to the low surface temperature at which self-sustaining flame propagation occurs when the dust cloud is heated and ignited.

Selection of Electrical Explosion proof Equipment
Industrial process and surface temperature control

7

Low ignition temperature of dust layer

GB∕T 16430
VDI 2263/ASTM E 2021

The ignition temperature of the dust layer reflects the sensitivity of dust to ignition when accumulated. After the dust layer catches fire, it usually does not explode on its own, but can become an ignition source for dust explosions.

Selection of Electrical Explosion proof Equipment
Industrial process and surface temperature control

8

Dust layer resistivity

GB/T 16427

The electrode in contact with dust per unit area is separated by a unit distance, and the resistance measured between the two electrodes is small.

Selection and use of electrical equipment suitable for combustible dust environments